Subject Index A ABEK-filters 237, 242 accident 172f., 177, 179, 183f. accidental release 102, 104 accumulation 69 acetaldehyde 72, 238, 291 acetic acid 47, 190 acetic anhydride 48, 132 acetone 53, 132, 174, 193, 221, 239, 272, 291 acetonitrile 195f., 221 acetyl chloride 75 acetylanthranilic acid 132 acetylene 75, 293 acrolein 39, 238, 280 acrylamide 62, 68, 242 acrylate 51 acrylonitrile 62, 148, 197, 278 active charcoal 280 active sampling 258, 280 acute 16 - lethal 79ff. - toxicity 375 adenoma 22 additive properties 79 ADN 320 ADNR 320 adolescents 204, 207 ADR 111, 320f. adsorption tubes 280 aerodynamic diameter 31 aerosol 97, 328, 346 aerosol cans 303 aflatoxine 26, 28 AGW 197 air sampling 256 alarm plan 172f., 177, 295, 298 alcohol 20, 25 aldrin 136f. algae 66, 67, 140 alkali - hexafluorosilicate 41 - hydrogen difluoride 41 - sulfuryl fluoride 41 alkylcellulose 293 allergen 50 - contact 16 - respiratory 16 allylalcohol 193 alumina 280 aluminum 293, 295 alveolar dust 31f. amendments on technical progress see ATP Ames test 29 aminobiphenyl 61, 98, 116, 129, 153, 181 2-aminobutane 238 2-aminoethanol 195 amitrol 46 ammonia 10, 41, 48, 58, 69, 194, 237, 272, 274, 293 ammonium - hydrogen sulfide 115 - nitrate 304 - sulfide 115 tert-amyl acetate 194 angioma 22 aniline 13, 69 animal feed 100, 102, 144 annex I 76ff. anthranilic acid 132 antibodies 16 antidotes 178 antimitotic drugs 201, 203 apron 223f. aquatic 365 - toxicity 375 Arbeits Schutzgesetz 155 Arbeitssicherheitsgesetz 156 aromatic amines 61 aromatic hydrocarbons 61 arsenic 39, 117, 130, 148, 198 - acid 61 - pentoxid 61 - trioxide 61 arsine 72 article 6 asbestos 25, 27, 34f., 43, 60ff., 99, 114, 129, 148, 151, 186, 197ff., 206, 289, 343 - actinolite 151 - anthophyllite 151 - chrysotile 151 - crocidolite 151, 152 - directive 149, 151ff., 198 - gruenerite (amosite) 151 - tremolite 151 asphyxiant 327 aspiration 46 assessment of risks see risk assessment ataxia 53 atopy 16 ATP 76 atrazine 68 auramine 182, 201 Ausschuss für Gefahrstoffe 196f. authorization 383 AX filters 235, 238ff. azinphos-ethyl 129 azo colorants 123 azo compound 331 B bacteria 20, 338 bacterial diseases 20 badges with direct indication 273 barium 195, 196 - peroxide 73 - sulfate 9 BAT values 200 BAuA 258 benomyl 68 benzaldehyde 44 benzene 13, 43, 61, 114, 129, 149, 187, 198f., 204, 272 benzidine 27, 60f., 98, 115f., 129, 153, 181 benzo[a]pyrene 59, 62, 68, 121 benzoquinon 69 benzyl alcohol 44 benzylamine 48 beryllium 43 Betriebssicherheitsverordnung 156 BGIA 285 BIA-Mappe 258 binapacryl 129 bio-hazard sign 159 bio-monitoring 173, 200 bioaccumulation 110 biocidal product 125 biocide 128 Biocide Directive 125 biodegradability 375 biological agents 156, 158f., 201f., 206 - directive 158 biological limit value see OEL bischloromethylether 61 black horehound 42 blade cut resistance 220 blastogenesis 18 blower-assisted filtering devices 230 blower-assisted respirator see respirator with blower body protection 176, 207 BOELV see OEL boron trihalogenides 39, 75 botulinus toxin 40 breakthrough 213 breast feeding women 156 breathing protection see respiratory protection bromine 11, 39, 195f., 274 bromoacetic acid 115 bromomethane 238 building block 343f. butadiene 61, 238 butane 72, 239 butanol 53 butanone 53, 193 2-butoxyethanol 193 2-(2-butoxyethoxy)ethanol 195 2-butoxyethyl acetate 193 butyl acetate 53 n-butyl acrylate 193 butyl rubber 214, 217f., 223 C cacao 293 cadmium 13, 97, 118, 129, 149, 198, 203, 293 - oxide 43 - sulfide 9 calcium - dihydroxide 190 - gluconate 178 calomel 44 caprolactam 58, 193, 242 captafol 129f. carbenazim 68 carbon - dioxide 195f., 278 - disulfide 43, 221, 239, 282, 291 - monoxide 20f., 43, 56, 201, 203, 235, 237, 239, 291 - tetrachloride 41, 122, 129, 132, 149, 198 carcinogen 16, 54, 91f., 98, 119, 156, 180, 181ff., 207 - restrictions directive 149 carcinogenic 77, 79f., 82, 109, 206 carcinogenicity 60, 80, 142, 362, 376f. carcinogens and mutagens directive 2004/37/EC 26, 180ff., 198, 201, 205, 290 carcinoma 22 carriage 112 carrier effect 169 CE 221 - label 157 - sign 208 CEN 225 cell cultures 158 cell proliferation 22f. cement 124 ceramic fibers 35 chemical agents 156, 166ff., 168, 173, 192, 201f. chemical agents directive 98/24/EC 149f., 153, 166ff., 182, 190, 197ff., 259, 290 chemical protection suits 157 chemical safely assessment 376, 382 chemical safety report 374, 376f., 379, 381f. chemically bound oxygen 251 chlordan 136f. chlordecon 136 chlordimeform 130 chlorfenapyr 129 chlorinated hydrocarbons 149, 170, 198, 278 chlorine 10f., 41, 58, 195, 237, 272, 274 - active 97 - dioxide 75 chloroacetic acid 69 chloroalkane 121, 123 chlorobenzene see monochlorobenzene 193 chlorobenzilate 130 2-chloro-1, 3-butadiene 238 chlorodifluoromethane 193 chloroethane 195 chlorofluorocarbon 132 chloroform 122, 129, 149, 198, 238, 278 chloromethane 239 chloroprene rubber 214 chlozolinate 129 choline 130 chromates 17, 63, 73, 195 chronic 16 - study 142 cilia 32 classification 6, 38, 76, 139, 377 classification limit 84f., 96 closed system 182f. CNS depression 53 CO filters 235 coarse dust 284 cobalt 52 collective measures 170f. combined filters 242, 254 combination filter 231 combustible - chemicals 290 - dust 165 - liquids 304 - solids 305 - substances 122 compatibility group 325 composition 102f. compressed - air bottles 248 - air line respirators 230 - gases 303 - oxygen 251 concentration limits - general 80 - substance-specific 83 container 322 continuous exposure control 265ff., 273 conventional method 79 corrosion 357 corrosive 47ff., 79ff., 109, 340, 355 - substance 304, 321 corrosivity 377 COSHH 196 cosmetic product 100, 102, 120, 125 creosote 99, 121, 129 cresols 190 crocidolite see asbestos cross-sensitivities of tubes 272 crotonaldehyde 69 CSA see chemical safety assessment CSR see chemical safety report cumene 193 cumulative 52 cupro-nickel mattes 182, 201 cyanamide 51, 195, 196 cyanide 13 cyanoacrylate 96 cyclohexane 53, 195 cyclohexanol 44 cyclohexanone 193 cyclones 285, 287 cyhalothrine 129, 130 cytotoxic 63 D danger symbol 38, 90f., 95 dangerous goods 95, 319, 322 Dangerous Preparation Directive 77f. dangerous - preparation 166 - substances 166 Dangerous Substance Directive 28, 37, 76, 181, 201 daphnia 66f., 140 DBB 118, 129 DDT 43, 69, 129, 136f. definition principle 78 deflagration 295 degradability 110 degradation 140, 213, 221 dentallaria 42 Derived No-EfFect Level see DNEL dermal 7, 10, 13 - absorption 191 - contact 182 - exposure 169, 171, 200 desoxyribonucleic acid (DNA) 22ff. detonation 294 detoxification 12 developmental toxicity 55, 142, 377 DFG 258 di-isocyanates 11 di-isopropyl ether 53 diazomethane 239, 280 diazonium salt 331 dibenzoyl peroxide 51, 74 1,2-dibromoethane 129 dichloroacetylene 74 dichlorobenzene 149, 193, 198 1,1-dichloroethane 193 1,2-dichloroethane 129 1,1-dichloroethylene 122 dichloromethane 221, 239 dicofol 129 dieldrin 136f. diethyl ether 72, 75, 193, 239, 291 diethylamine 195f., 221, 239 diethyleneglycol dinitrate 74 diffusion samplers 283 diffusion tubes 272 dihydrogen selenide 194 dimethyl ether 72, 193 dimethyl formamide 9, 56, 203 dimethyl sulfate 39, 62, 280 N,N-dimethylacetamide 193 dimethylamine 193, 239 dinitro-ortho-cresol 39 dinitroaniline 39 dinitrobenzene 39, 74 dinitrogen trioxide 39 dinoseb 56, 129 dinoterb 56, 129 dioxane 64, 75 diphosphorus pentaoxide 195f. diphosphorus pentasulfide 195f. direct-reading tubes 263, 267 Directive 3, 5 directly indicating tubes see direct-reading tubes disinfectants 17 disposal 102, 111, 178 dissolved gases 303 disulfur dichloride 51 DNA 29 DNEL 377, 381, 383 DNOC 129 Doll 25 dosimeter tubes 273 drug 20 dust explosions 294 dust filter see particle filter dust sampler 285f., 288 dysplasia 24 E earthing 293 EC Index No. 77 EC number 90f. EC50 67 ECB 76, 89 ECOSOC 320 eczema 17 EDEXIM 130 EDX 289 effect - acute 13 - local 7 - systemic 7 - teratogenic 18 EINECS 6, 77, 90f., 103, 139, 371 electrochemical sensors 275f. electromagnetic fields 154, 156 electrostatic discharge 293 ELINCS 6, 77, 90f., 103 elutriators 288 embryonic - effects 20 - stage 18 emergency 172, 177, 183 emergency escape or first-aid signs 160 emergency exits 296 endocrine-disrupting 383 endogenous factors 24 endrin 137 environmental 79 - properties 86 - protection 178 - toxicity 66 epichlorhydrin 51, 62 epidemiological investigations 54, 60 ephedrine 132 epoxide 61 epoxy constituents 97 ergometrine 132 ergot 42 ergotamine 132 ethane 278 ethanediol 193 ethanol 13, 45, 291 ethyl - acetate 221, 272, 291, 293 - ether 132 - nitrate 74 - nitrite 74 ethylamine 193, 239, 293 ethylbenzene 193 ethylene 293 - imine 239 - oxide 68, 129, 239, 273 ethyleneimine 68 ethylenglycol 58 ethylenoxide 62 ethylglycol 56 European Commission 1ff. European Council 1ff. European Court of Justice 3 European Parliament 1ff. European Treaty 3 European Chemical Bureau see ECB experimental testing 79 explosion 292ff. - hazards 154, 164, 172 - protection document 164f. - range 292 explosive 74, 79, 345 - atmospheres 156, 164, 170ff., 277, 293 - atmospheres directive 1999/92/EC 164 - substance 321, 324 - zones 165 explosivity 377 exposure 173, 182, 186f., 202 - assessment 264 - control 102, 106 - measurements 149, 166, 170f., 173, 182, 186, 203, 256ff., 280 - peaks 262 - records 152, 173 - scenario 382 extremely flammable 71, 79 eye protection 175f., 207ff. F face protection 207, 208ff. face shield 107, 157, 175, 208ff., 212ff. fentin acetate 129 fenvalerate 129 ferbam 129 fertility 21, 59, 142, 377 fetal effects 20 fetal period 19 fiber measurements 289 fibers 31f., 34 fibroma 22 FID 263, 278f., 283 film glove 220 filtering half masks 227, 229 filtering respirators 230 fine dust 31, 284, 287 fire - extinguishers 296 - fighting measure 102, 104 - hazards 172 - prevention signs 163 first-aid 155, 172, 177 - measure 102f. - signs 163 fish 66f., 140 flame ionization detectors see FID flammability 377 flammable 73, 79, 99, 345f., 348 - liquid 303, 321, 329 - solid 303, 321, 330 flashpoint 71, 108, 290ff. flour 17 - dust 295 fluorides, inorganic 194 fluorine 39, 75, 194 fluorine elastomer 214, 217 fluoroacetamide 130 fluoroacetic acid 39 food additive 125 foodstuff 100, 102, 144 formaldehyde 41, 50f., 58, 239, 273, 278, 280 formic acid 48, 195f. foxglove 42 framework directive 80/1107/EEC 147ff., 153, 188 framework directive 89/391/EEC 147, 149, 153ff., 156ff., 164, 166, 179, 181, 200 full-face masks 212, 223, 226, 228f., 247f., 251, 255 fungi 126, 338 G gamma rays 20, 23 gas 321f., 326, 345, 347 - cartridge 323 - corrosive 328 - detector pumps see gas monitoring pumps - filter 175, 231, 235ff., 240f. - filtering half masks 238 - flammable 328 - monitoring pumps 269 - oxidizing 328 gasoline 204, 291 Gefahrstoffverordnung 156, 163, 196f. genotoxic 22, 64 Germany 155, 196f., 200, 258, 264, 299 GHS 343 glass wool 35 glasses see safety glasses globally harmonized system see GHS glove material 214, 216f. gloves 107, 157, 174f., 186, 213ff. - powdered 215 glutaraldehyde 50, 69 glyceryl trinitrate 40, 74 glycidol 59 glycidylether 51 glycol 44, 291 - dinitrate 74 - ethers 203 goggles 107, 157, 175, 208ff. gold 289 Great Britain 155, 196 guideline 5 gypsum 289 H half mask 226, 229, 248 halogens 69 halon 132 hand protection 176, 207 handling and storage 102, 104 hardwood dust 61, 181f., 187, 199, 201 harmful 38, 44ff., 92 hazard 167 - identification 102f. - pictogram 344 - statement 344 hazardous chemical agents 166 HCB 43, 64, 70, 136f. HCH 129, 136f. HDI 41 health record 187 health surveillance 155, 166, 169f., 173, 180, 186f. heptachlor 136f. heptane 46, 193, 221 heptane-one 193 hereditary diseases 64 hexabromobiphenyl 136f. hexachlorobenzene see HCB hexachloroethane 122, 129 hexamethylene diisocyanate 52, 273 n-hexane 46, 195 highly flammable 72, 79 highly toxic 338 hold-up time 11 hormones 24 hot surface 291 HSC 196 HSE 192, 196, 256 human endo-parasites 158 hydrobromofluorocarbon 132 hydrocarbon - chlorinated 13, 99 - halogenated 98 hydrochloric acid 47, 132, 272, 275 hydrocyanic acid 15, 274, 276 hydrofluoric acid 9, 178, 210, 274 hydrogen 235, 291, 293, 295 - bromide 194 - chloride 10, 194, 237 - cyanide 39, 237 - fluoride 10, 39, 48, 194 - sulfide 15, 39, 237, 272, 274 hydroquinone 69 I IATA 111, 320 IBC 322f. IC50 67 ICAO 111, 320, 323 identified use 376f. ignition 72, 104 ignition temperature 291 IMDG 111 IMDG-code 320, 323 IMO 320 impingers 280 incidents 172 industrial chemical 128 infectious substance 304, 321, 338 infiltration stage 24 inflammation 49 information of workers see instructions information rights of employees 158, 179f, 186 information signs 160 infrared detectors 277 ingredient 102 inhalable - fraction 284f. - particles 32, 284 initiation stage 23 inhalation 182, 187, 200 inhalative 7, 10, 13 INRS 256 inspections 183 instructions 148, 155, 166, 173ff., 179, 185f. intermediate 141, 378 intrinsic properties 89 iodine 11, 44 iodomethane 239 IOELV see OEL ionizing radiation 201, 206, 213 iron pyrites 293 irritant 49, 80f., 92, 109 irritation 357, 375, 377 - eye 140 - skin 140 irritative 79 isoafrole 132 isobutyric acid 44 isocyanate 97 isocyanides 11 isopentane 195 isopentyl acetate 193 isophorone diisocyanate 273 isopropanol 182, 201, 293 isopropyl alcohol see isopropanol J Johannesburg Convention 32, 284f., 287 K ketene 239 L label 90, 95f. labelling 139, 344, 377 latency time 24 latent effect 11 latex see natural rubber LC50 67 LD50 13ff. lead 13, 96, 149, 173, 180, 198ff., 202f., 206 - additive 150 - alkylated lead compounds 150 - arsenate 150 - azide 74 - carbonate 116 - chromate 56 - diacetate 56 - directive 149ff. - oxide 150 - sulfate 116 - tetraacetate 56 leakage 177, 236, 297 leather gloves 213, 215, 220 legal classification 76 lens material 208f. lenses 209 lethal dose 13 lethargy 53 limit threshold 55 Lindane 69, 130, 136 lipoma 22 liquefied gases 303 liquid absorber 280 liquid oxygen 251 list principle 76 lithium aluminium hydride 72 lithiuim hydride 190 liver 12 LOAEL 192 local lymph node assay (LINA) 18 long-term monitoring 272 lower explosion limit 292 Lowest Observable Adverse Effect Level see LOAEL LSA 340 lysergic acid 132 M macrophages 33 Magnusson-Kligmann test 18 MAK-Kommission 188, 192, 197 maleic - anhydride 44, 52 - hydrazide 130 man-made mineral fibers see MMMF mandatory signs 160, 162 manganese dioxide 44 masks see respirator masks maternal toxicity 55 maximum explosion pressure 293 maximum tolerable dose see MTD MDHS series 256 meadow saffron 42 measurement plan 259f. mechanical injuries 208 median lethal dose 14, 38 medical device 100, 125 medical examinations 235, 246, 255 medicinal 120 medicinal product 100f., 125, 144 MEL 196 mercury 9, 41, 117, 130, 149, 198, 201, 203, 237 - compounds 13 - dichloride 40 - fulminate 74 mesitylene 193 mesothelioma 35 metastases 22 methacrylate 51 methacrylic acid 48 methamidophos 130 methane 278, 291, 295 methanol 13, 195f., 221, 239, 272, 293 2-(2-methoxyethoxy)ethanol 195 (2-methoxymethylethoxy)-propanol 194 2-methoxy-1-methylethyl acetate 193 1-methoxy-2-propanol 193 methyl - acetate 239 - bromide 41, 132 - butyl acetate 194 - chloride 278 - cyclohexane 46 - glycol 13 - isocyanate 72 - lithium 72 - parathion 130 methylene - chloride 282 - diisocyanate 273 3,4-methylenedioxyphenylpropan-2-one 132 2,2'-methylene-diphenylene-diisocyanate 52 methylethyl ketone (MEK) 132 methylglycol 56, 203 5-methyl-3-heptanone 194 5-methylhexane-2-one 193 methylmercury 56, 203 4-methylpentane-2-one 193 Metropol 258 micro-organism 126, 158, 213, 304 mineral fibers 289 minimum ignition energy 292f. mirex 136f. miscarriage 21 mixed storage 290, 299ff. MMMF 27, 34, 61 mold 42 monochlorobenzene 192ff. monocrotophos 130 monolinuron 130 monomethyldibromodiphenylmethane 119, 129 monomethyldichlorodiphenylmethane 119 monomethyltetrachlorodiphenylmethane 119 Montreal Convention 132 morpholine 195 mouthpiece assembly 227, 254f. MTD 27, 63 multiple-stage process 24 mutagen 54, 91f., 98, 120, 156, 181ff. mutagenic 77, 79f., 82, 109, 206 mutagenicity 80, 140, 362, 375, 377 mutations 29 N N.O.S. 323 name - chemical 90, 96 - company 90 - trade 96 nano-particles 32 naphthalene 190, 242 naphthalene diisocyanate 273 2-naphthylamine 60f., 98, 115, 129, 153, 181 narcotic - drugs 128, 131 - effects 53 natural rubber 214, 217f. neopentane 195 neoprene 223 neoprene glove 220 nickel 52, 119, 149, 198 - dioxide 61 - disulfide 61 - sulfide 61 - tetracarbonyl 203 - trioxide 61 nicotine 13, 39, 195f. NIOSH 258 nitric acid 47, 74, 195 nitrile rubber 214, 217f., 223 o-nitrobenzaldehyde 115 nitrobenzene 13, 39, 44, 195f. 4-nitrodiphenyl 98, 116, 129, 153, 181 nitrofen 130 nitrogen 235, 278 - dioxide 15, 39 - monoxide 189f. - oxide 11 N-nitrosamines 26f., 61 N-nitroso compound 331 nitrous gases 237, 239, 272, 276 no observed adverse effect level see NOAEL no observed effect level 14 NOAEL 14, 192, 256 noise 154, 156, 201 non-additive properties 79, 82 non-ionizing radiation 201 nonylphenol 124 norephedrine 132 normal handling and use 90 notification 6 nutmeg 42 O occupational exposure level see OEL occupational exposure limit value see OEL occupational hygiene 185 octabromodiphenylether 123 octane 46, 53 OEL 106, 148, 150, 152, 166f., 169, 171f., 183, 187ff., 207, 225, 233f., 236, 238, 241, 245, 247f., 256, 261, 264f. - binding occupational exposure limits (BOELV) 150, 167, 173, 180, 197ff. - biological limit values (BLV) 106, 167, 173, 180, 187, 199ff. - dermal exposure 171 - directive 91/322/EEC 153 - indicative limit values 153, 189ff. - indicative occupational exposure limits (IOELV) 167, 192, 194 OES 196 on-site isolated intermediate 378f. oral 7, 13 organic peroxide 304, 321, 336 organostannic 118 OSHA 258 osmium tetroxide 40 overalls 223 overload 33 overpack 323 oxalic acid 195f. oxidizing 73, 79, 346, 352f. - potential 378 - substance 304, 321, 335 oxygen 12, 278 - chemically bound 251 - compressed 251 - liquid 251 ozone 11, 274 ozone layer 70, 132 P package 95, 323 packaging 323 - group 322, 330, 333, 335, 337, 341 PAH 26, 125, 137, 182, 201 paint 96 paint spraying 249 paint strippers 170 paraformaldehyde 293 parasite 338 parathion 69, 130 particle filter 107, 175, 231ff. - half masks 232ff. particulate matter 149 passive sampling 280, 283 patch test 18 pathogens 338 PBB 129 PBT 376, 378, 383 PCB 59, 100, 113, 136f. PCDD 137 PCDF 137 PCT 100, 113, 129 penetration 213, 220, 225 pentabromodiphenylether 123 pentachloroethane 122 pentachlorophenol 118, 130 pentachlorophenyl 98 pentane 46, 53, 72, 195, 239 pentyl acetate 194 perchloric acids 74 perinatal 20 permanganates 73, 74 permeation 213, 216, 221, 225 - rate 213 - time 213, 216f., 219 permethrin 130 peroxide 75, 354 persistence 69, 110 persistent organic pollutants see POP personal - air sampling 258, 261, 272, 280ff., 283 - precautions 104 - protection 106 - protective equipment 102, 106, 154, 156f., 159, 170ff., 175f., 178, 183f., 186, 207ff., 297 personal protective equipment directive 89/656/EEC 157f. pesticide 102, 128 Peto 25 phagocytosis 34 phase-in 373 phenol 9, 13, 193 phenylacetic acid 132 1-phenyl-2-propanone 132 2-phenylpropene 193 phosgene 11, 15, 39, 193, 239, 273ff. phosphamidon 68, 130 phosphine 51, 195 phosphoric acid 48, 194 phosphorus 75, 293 - chlorides 11 phosphorus pentachloride 195f. photoionization detectors see PID phthalic acid anhydride 52 physical agents 201f. physical radiation 20 physico-chemical properties 79, 140, 375 PIC Convention 127, 130 picric acid 74, 190 pictograms 220ff. PID 263, 277ff., 283 piperazine 48, 193 piperidine 48, 132 piperonal 132 placenta barrier 19 placing on the market 6 plant protection product 125 platinum 190 PNEC 377, 381, 383 PNOC 33 polybromobiphenyl 115 polychlorinated biphenyl see PCB polychlorinated dibenzo-p-dioxin see PCDD polychlorinated dibenzofuran see PCDF polychlorinated terphenyl see PCT polychloroprene 214, 217f. polycyclic aromatic hydrocarbons see PAH polyethylene (PE) 214, 295 polymer 143f. polyvinyl alcohol (PVAL) 214 polyvinyl chloride (PVC) 197, 214, 223 POP 136f. POP Regulation 136 postnatal 20 potassium 75 - cyanide 39 - hydroxide 47 - perchlorate 74 - permanganate 132 - peroxide 252, 255 PPE see personal protection equipment pre-registration 374 Predicted No-Effect Level see PNEC pregnant 18ff., 156, 179, 200, 202 pregnant and breastfeeding women directive 92/85/EEC 200ff. preneoplasmatic stage 24 preparation 6, 77f., 96 preparation directive 181 priority of measures 170 process-oriented research and development 144 professional disease 173, 187 prohibition signs 159f. promoter 23 promotion stage 23 propanal 239 propane 72, 239, 278, 293, 295 propanol 53 propham 130 propionic acid 47f., 193 propyl acetate 53 propylbenzene 46 propylene oxide 71f., 239 protection level 216f., 221 protective - clothing 186, 223ff. - measures 169f. - suits 223ff. pseudoephedrine 132 psychotropic substances 128, 131 puncture resistance 220 purple book 343 pyrazophos 130 pyrethrum 195f. pyridine 190 pyrophoric 72, 332, 350 Q quarter masks 227, 229 quintozene 130 R R-phrase 38, 91, 93, 111f., 175f. radiation 205 radioactive 339 - material 321 - substance 100, 102, 304 Raney nickel 72 REACH 3, 371 - implementation process see RIP reactivity 102, 108 reduced test package see RTP registration 373 Regulation 3 renotification 145 repeated dose toxicity 140 reproduction 77, 80, 82 - toxicity 55, 79f., 109, 363, 375 resistance to abrasion 220 resorcinol 195f. respirable - fibers 289 - particles 284, 287 - fraction 284 respirator 157, 186, 203, 226ff., 243 - compressed air 248ff. - for self-rescue 252ff. - masks 226 - regenerating 251 - self-contained 226, 245ff. - with blower 243, 245 respiratory - helmets 230 - hoods 230, 235, 254 - protection 107, 176, 183, 207, 226ff., 266 - protection devices 175 - protective helmet 227 - protective hood 227 - protective suits 227 - suits 230 Responsible Care 299 rickettsia 338 RID 111, 320, 323 RIP 371 risk 167 risk assessment 155, 159, 164, 166ff., 172f., 182ff., 187, 200, 202, 204, 266, 290f. Rotterdam Convention 127 RTP 141 S S-phrase 91, 93, 111, 176 SADT 324 safety - cabinets 307 - data sheet 100, 167f., 173ff., 295, 305, 380, 382 - data sheet directive 91/155/EEC 167 - glasses 208f., 210ff. - operation instruction see instructions - sign directive 92/58/EEC I59ff., 184 - signs 159ff., 176, 183 safrole 132 sampling - heads 285ff. - methods 258 - pumps 281f. - techniques 258 - tubes 262f. saponin 115 sarcoma 22 scientific research and development 144 SCO 340 SCOEL 190ff., 196, 199 segregated storage 307 self-contained breathing apparatus see respirator self-contained self-heating 332, 351 self-reactive 349 - substance 321, 330 SEM 289 sensitization 16, 50, 79, 140, 375, 377 sensitizing 109 sensitizer 92, 98, 361 separate storage 305 short-term concentrations see short-term measurements short-term exposure 264, 272 short-term measurements 262ff. SIEF 374 signal words 344 silica 280 silver 194ff. single-use gloves 214, 219f. sister chromatid exchange 29 skin - absorption 201 - notation 191f., 194f. skull-and-crossbones danger symbol 38, 338 sleeves 223f. smokes 31 smoking 20 sodium 75 sodium - azide 194 - chlorate 74, 255 - chloride 45 - hydride 72 - hydroxide 47 - hydroxide soln. 221 - perchlorate 74 solid desensitized explosives 321, 330 spectacles 157, 175, 208ff. spontaneous combustion 332 squirting cucumber 42 stability 102, 108 stationary sampling 258, 288 STEL 191f. Stockholm Convention 136 storage 183, 290, 295ff. - classes 299ff. - plan 295f. stretching behaviour 220 strong acid process 201 strychnine 39 styrene 58 sub-acute 16 - study 375 sub-chronic 15f., 142 - study 375 substance 5 substitution 170, 182f. sugar 295 sulfohydrazide 331 sulfotep 194 sulfur dioxide 10, 41, 237, 272, 274 sulfuric acid 47, 64, 132, 221 supplied-air respirators 226 supply chain 381 swelling 213 SX-fdters 239 T 2,4,5-T 130 TCDD 24, 39f., 64 TDI 41 tear resistance 220 Technical Progress Committee see TPC tecnazene 130 temperature classes 165, 291 teratogenic effects 20 teratology study 142 terpentine oil 46 2,3,7,8-tetrachlorodibenzodioxin see TCDD tetrachloroethane 122 tetrahydrofurane 58, 75, 193, 221 thermodesorption 260, 263, 283 thionyl chloride 48, 51 thiram 68 thoracic particles 284 threads 228 threshold limit values see OEL time-weighted average see TWA tin - inorganic compounds 190 - tetrachloride 48 titanium tetrachloride 75 TNT 74 toluene 44, 58, 124, 132, 195, 221, 272, 291 toluene diisocyanate 273 p-toluenesulfonic acid 48 toluidine 62 2,4-toluidenediisocyanate 52 total dust measurements 285 total inhalable dust 31 toxaphen 136f. toxic 38, 41ff., 91, 337f., 356 - substance 304, 321 - to reproduction 54, 91f., 99, 120 toxicokinetic 140 toxicological studies 140 toxification 12 TPC 76 tracheo-bronchial dust 31 training of workers 173, 185f. transport 102, 111, 183 transported isolated intermediates 379 TRGS 174, 197, 200, 299 tribromomethane 41 trichlorobenzene 125, 193 trichloroethane 122, 129, 132, 193 trichloromethane 193 trichlorosilane 51, 75 triethylamine 48, 193 trimellitic acid anhydride 52 trimethylamine 72 trimethylbenzene 193f. trinitrobenzene 74 trinitrocresol 74 triorganostannic compounds 129f. tris-aziridinyl phosphinoxide 115, 129 tris-(2, 3-dibromopropyl)phosphate 114, 129 tumors 22 TWA 191, 196, 262 two-generation study 142 U Ugilec 119f., 129 ultra-violet radiation 23 UN Number 321 United Kingdom see Great Britain unsaturated polyester resins 170 upper explosion limit 292 V vanadium pentoxide 44 varnish 96 VCI 299 Ventilation 105, 171, 183, 186 very toxic 38ff. veterinary 120 - products 125 vibration 154, 156, 201, 205 vinyl chloride 61, 72, 114, 187, 197, 199, 239, 266, 272 viral diseases 20 virus 20, 23, 126, 338 vitamin A 20f. viton see fluorine elastomer vPvB 376, 378, 383 W warfarin 44, 56 warning signs 159, 161, 165, 184 waste 100, 102, 111, 178 WEL 196 work equipment directive 89/655/EEC 156 X X-ray 20, 23, 25, 64 xylene 193f., 291 Y young people protection directive 94/33/EC 204ff. Z zinc chromate 61 zineb 130 ziram 68 zirconium 293
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