DeutschesFachbuch.de : Photofunctional Transition Metal Complexes Structure and Bonding

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Contents
Remarkable Luminescence Behaviors and Structural Variations of Two-Coordinate Gold(I)...
A. L. Balch 1
From Photoinduced Charge Separation to Light-Driven Molecular Machines
E. Baranoff-F. Barigelletti • S. Bonnet • J.-P. Collin • L. Flamigni • P. Mobian • J....
Metal-Based Photoswitches Derived from Photoisomerization
S. Kume • H. Nishihara 79
Transition Metal Complexes for Photovoltaic and Light Emitting Applications
M. K. Nazeeruddin • M. Grätzel 113
Conjugates of Heme-Thiolate Enzymes with Photoactive Metal-Diimine Wires
S. M. Contakes • Y. H. L. Nguyen • H. B. Gray • E. C. Glazer • A.-M. Hays • D. B. Goo...
Luminescent Transition Metal Complexes as Biological Labels and Probes
K. K.-W. Lo 205
Author Index Volumes 101-124 247
Subject Index 257
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Subject Index
AAcetylide-Pt(II)-terpy centre 62
Amine oxidase, Arthrobacter globiformis 179
Anisotropy probes 220
Au(I) centers, closed-shell 2
Au 3 I stacking, trimeric molecules 21
Au 3 I (n-Pent-N=COMe)3 11
Aurophilic interactions 2
Azobenzene-attached complexes 92
BBiotin derivatives, luminescent 2332, 2'-Bipyridinium, bridged 44
2, 6-Bis( 1-methylbenzimidazol-2' -yl) pyridine 1242, 6-Bis(4' -phenyl-2' -quinolyl)p...
CCatenanes 41, 69
- ruthenium(II)-containing 72
Charge separation 44
- photoinduced 41
Chromene-attached complexes 81
Citrulline 195
Cu(I)-phen-type complexes, luminescent 60
Cytochrome c, ruthenium-modified 218
Cytochrome P 450, catalysis, electron transfer 180
- class II drug metabolizing 178
Cytochrome P 450 CAM 177
Cytochrome P 450 reductase (CPR), FAD containing 178
DDecoordination, photoinduced, catenane 72
Di-p-anisylamine (DPAA) 45
Diarylethene-attached complexes 87
Dicyanoaurate, tunable luminescence 5 Di-(2-(3, 6-dimethoxyphenyl)ethenyl)-2, 2' bipy...
2, 4-Difluorophenyl-4 dimethylaminopyridine ligand 160
Dissociative excited states 64
cis-Dithiocyanato bis(2, 2'-bipyridine-4, 4'-dicarboxylate)Ru(II) complex(2) 138
cis-Dithiocyanato bis(4, 4' -dicarboxy-2, 2'- bipyridine)Ru(II) 130
DNA, photocleavage, guanine oxidation 207
DNA labels 210
Dye sensitization 114
Dye-sensitized solar cells 113
- conversion efficiency 120
- fabrication 117
- solid state 142
EElectrochemical sensors, molecular wires 179
Electrolytes, solvent-free 146
Electron acceptor/donor 43
Electron tunneling wires 178
Enzyme, wire-binding specificity 177
Enzyme inhibitors, molecular wires 179
Enzyme:wire conjugates 179
FFlash-quench methods 179
Fluorescent sensors, molecular wires 179
Förster-type RET quenching 207
GGold(I) complexes, two-coordinate 1
HHABA, avidin 233
Heme-thiolate enzymes, conjugates 177
Hole conductors 146
HOMO 121
- levels, tuning 161
Horseradish peroxidase, ferryl intermediates 178
IIncident monochromatic photon-to-current conversion efficiency (IPCE) 119, 140
Indole-binding proteins, probes 240
Iodide/triiodide redox system 116
Ionic liquids, solvent-free electrolytes 146
IPCE 119, 141
Ir, electron relay 56
- photoactive centre 59
Ir/Ru 41
Ir-bis-terpyridine derivatives 45
Ir(terpy) 53
- electron relay/photoactive centre 44
Ir(III)-cyclometalated complexes 44, 225
- luminescent 225
Iridium complexes, controlling quantum yields 163- tuning of phosphorescence colors 1...
Iridium polypyridine complexes, cyclometallated, luminescent 218
Iridium triplet emitters 113
KK[Au(CN)2], MCD spectra 3
LLigand-bridged complexes 36
Light-driven molecular machine 41
Light-emitting electrochemical cells 113- device architecture 170
Linear two-coordinate complexes in solution, absorption/luminescence 3
Lipoxygenase 179
Luminescence, crystalline polymorphism 6
- frozen solutions 31- ionic Au(I) complexes, counter ion effects 25
Luminescent labels 223
Luminescent linkers, nucleosides 210
Luminescent reporters 208
Luminescent wires, metalloproteins 229
LUMO 121
MMagnetic circular dichroism (MCD) spectra, colorless Au(I) complexes 3
Metal complex 79
Metal-diimine molecular wires, photoactive 177
Metalloenzymes 179
Metalloproteins, electron transfer 218- luminescent wires 229- photoinduced electron-...
Metal-to-ligand charge transfer (MLCT) 3
- photoexcitation 116
Methyl viologen (MV) electron acceptor 45
Microperoxidase-8, ferryl intermediates 178
Molecular machines 43
- light-driven 41- prototypes, ruthenium-based, light-driven 64
Molecular sensitizers 120
Molecular wires, cytochromes P 450 180
- dansyl-terminated, multiple electron transfer 177- fluorescent sensors 179
- inducible nitric oxide synthase (iNOS) 195
- photoactive, metal-diimine 177
- probing enzymes 178
Multi-mode function 79
Myeloperoxidase 179
NN 3 dye 139
NADPH reducing equivalents 178
Naphthalenediimide 64
Nitric oxide synthase, inducible (iNOS) 177, 195- catalytic cycle 195
Nucleosides, luminescent linkers 210
OOLEDs 113
- device architecture 165
- iridium complexes 149, 164
- triplet emitters 149
Oligonucleotides, post-modification 214
Organic light-emitting diodes see OLEDs
Organic photochromic molecules 107
Os(II) bis-terpyridine 45
Oxygenase 178
PP 450, catalysis, electron transfer 180- class II drug metabolizing 178
P 450 CAM 177
PH 2 -Ir(III)-PAu 4+ 56
Phenothiazine (PTZ) 44
Phosphorescence colors, anionic Ir complexes 158
Photoactive centre 43
Photochemical ligand exchange 65
Photochromism 79
Photocurrent, action spectra 140
- density 120- short circuit 139
Photoisomerization 79
Photon-to-current conversion efficiency (IPCE) 119
Photosubstitution-isomerisation 69
Photoswitches, metal-based 79
Photovoltage 119
- open circuit 119
Photovoltaic properties 113, 139
Platinum-based probes 231
Platinum(II) terpyridine complexes 227
Polypyridyl complexes, TiO 2 oxide surface 136
Probing open states 187
Protein labels 218
Protein probes 229
Pseudo-rotaxane 60, 70
Putidaredoxin 229
PZn-Ir(III)-PAu 4+ 56
RReporters, luminescent 208
RET quenching, Förster-type 207
Rhenium wires, iNOSoxy 199
Rhenium(I) iodoacetamide sulfhydryl groups 221
Rhenium(I) perfluorobiphenyl diimine 229
Rhenium(I) polypyridine biotin 233
Rhenium(I) polypyridine isothiocyanat 216
Rotaxane 41
[Ru(diimine)3]2+ core, light-driven unthreading 70
Ru(II) bipyridyl dye, sensitizer 118
Ru(II) bis-terpyridine complexes 45
Ru(II) complex, scorpionate terpyridine ligand 65
Ru(II) diimine adamantane 229
Ru(II) polypyridine isothiocyanate 223
Ru(II) polypyridyl complexes, 2, 2' -bipyridyl-4, 4' -dicarboxylic acid/thiocyanate l...
Ru(II)-tris-bidentate chromophores 62
Ru(terpy)(phen)-incorporating ring 67
Ruthenium-azurin 219
Ruthenium-based light-driven molecular machine prototypes 64
Ruthenium sensitizers 113
SScorpionate 41
Sensitizer, catalytic cycle 145
- spectral response 122
Sensitizer-tethered substrates 178
Short circuit photocurrent 139
Solar cells, dye-sensitized 113, 120
- TiO 2 -based, panchromatic charge transfer sensitizers 121
Solvoluminescence, Au 3 I (MeN=COMe)3 16
Spectral response 122
Spirooxazine-attached complexes 81
Spiropyran-attached complexes 81
Stabler-Wronski effect 144
Stilbene-attached complexes 92
Surface chelation, polypyridyl complexes, TiO 2 oxide surface 136
TThermal ligand exchange 65
TiO 2 -based solar cells, panchromatic charge transfer sensitizers 121
Tris-[Ru(4, 4'-dicarboxy-2, 2'-bipyridine)3 ] 122
ZZinc porphyrin 58
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