DeutschesFachbuch.de : Sulfur-Mediated Rearrangement I

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Contents
Sulfur is More Than the Fat Brother of Oxygen. An Overview of Organosulfur Chemistry
E. Schaumann 1
Recent Advances in Pummerer Reactions
S. Akai • Y. Kita 35
1,2-Sulfur Migrations
A. W. Sromek • V. Gevorgyan 77
1,3-Sulfur Shifts: Mechanism and Synthetic Utility
S.K. Bur 125
Author Index Volumes 251-274173
Subject Index 183
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Subject Index
AAcetogenin 38
Acetyl coenzyme A 3
Acetylation 36
Acyl coenzyme A 3
Acylcyclopropanes 5
- S-Adenosylmethionine 3
Allyl alcohols 25
Allyl sulfides 126
Allyl sulfones 148
Allyl sulfoxides 25, 143
Allyl thioethers 79
Allyl thiols 81
Allylic reversal 127
- 1, 4-Aminoalcohols 16
- ß -Aminoenones 23
- ß -Aminosulfoxides 65
Aniline 57
Arylsulfanylindolenine, sulfenamide 128
Asymmetric reaction 35
- N-Benzensulfinyl-tosylamide 15
B
N-Benzensulfinyl-tosylamide 15
Benzimidazoles 128
Benzofuran neolignans 57
Benzothiazines 132
Biomolecules, sulfur-containing 4
- Biotin 3
Bis(o-aminophenyl)disulfides 132
Bond-forming reactions, carbon-carbon 35
- interintramolecular 41, 42
- Pummerer reaction-initiated 41
CCamphorsulfonic acid 18
Carbanion stabilization 12
Carbene, 1, 2-sulfur shift 81
Carbenium ions, stabilization 10
Carbon-carbon bond-forming reaction 35
Carbonyl vs. thiocarbonyl chemistry 25
Cephalosporin 114
Collidine 66
Cyclopropane 5
Cyclopropanethiocarboxamides 28
Cyclopropanethione 28
Dde Groot rearrangement 83
Dewar thiophene ligands 134
Diaryl disulfides 138
Dibromothiopropane 82
Difluoroiodotoluene 70 - 2, 3-Dihydro-l, 4-dithiine 84
Dihydro-1, 4-thiazine rearrangement 131
Dihydroisothianaphthene dioxide 21
Dihydropyrans 16
p-Dihydroquinones 52
Dihydrothiophene 130
Dimethyl sulfoxide 7
Dimethyl(methylthio)-sulfonium
tetrafluoroborate (DMTSF) 10
- 1-Dimethylamino-naphthaline 23
Dimethyl-methylen-sulfurane 5
Diphenyldiazomethane 28
- 4, 4'-Di-tert-butyl-biphenyl, lithiated (LDBB) 23 - 1, 3-Dithiolanes, anionic cyclo...
Domino reactions 45
EElectrophiles, non-carbon 11
Episulfide 130
Exomethylene 1, 4-dithiane 84
FFluorination reactions, Pummerer
- reaction-initiated 69
- a-Fluorosulfides 69
Fredericamycin A 55
HHetarenes 3
Heterocycles, thio-substituted 79
Hexafluorothioacetone 26
IImidazolines 64
Indoles/indolenines 127 - 2, 3-O-Isopropylidene-D-glyceraldehyde 15
Isothiazolones 64
LLeaving group, sulfur 21
Linchpin chemistry 14
- 5-Lithiobenzofurans 57
- a -Lithiosulfoxides 66 - 2-Lithio-l, 3-thiazole 15
MMenthyl p-toluenesulfinate 17
Mesylate 129
Methyl p-tolyl sulfoxides 37
- S-Methyl-S-phenylsulfoximine 18
Morin rearrangement 77, 114
NNeolignans 57
OOrganometallic substrates 168
Organosulfur 1
Oxathiane, oxathioacetal ring expansion 84
Oxathioacetals 84
Oxidation states 9
Oxiranes 4
PPenicillin to cephalosporin 114
Perfluorination 92
Phenol ethers 52
Phenylsulfinylfurans 60
Pinacol 11
Polyoxamic acid 69
Pummerer reactions, asymmetric 48
- interrupted 63
Pummerer-type reactions, aromatic 52
Qo-Quinodimethane 21 Quinone O, S-acetals 53
RRadical sulfur migration 120
Ramberg-BÄncklund reaction 25
Ritter reaction 91
Rolliniastatin 38
SSelenium 29
Selenoxides 29
Shahamin K 11 2-Silylthioacetals 13
Sodium methylsulfinylmethylide 13
Sphingosines 69
- N-Sulfanylbenzimidazole derivatives 128
Sulfenamide 128
Sulfenic acids 8
Sulfides, chiral 6
- , cyclic 130
- , 1, 3-shift 125
Sulfilimines 9
Sulfimines 9
Sulfinic acids 8
Sulfinylimines, chiral 18 - 5-Sulfinylindoles 60
- p-Sulfinylphenols 52
- 2-Sulfinylthiophene 603-Sulfolenes 23
Sulfone, 1, 3-shift 125
Sulfonic acids 8
Sulfonium salts, organometallics 21
Sulfonyl migration, gem-disulfonyl
- compounds 116
Sulfoxides, acyclic 143
- cyclic 146
- optically active, chiral auxiliaries/carbonyl equivalents 37
- 1, 3-shift 125
Sulfoximines 9, 15
Sulfoxonium ylides 5
- Sulfur, chiral 16
Sulfur migration 77
- carbenoid center 103
- carbohydrates 94
- elimination 81
- fragmentation/recombination 109
- heterocycles 100
- perfluorination 92
- radical 120
- Ritter reaction 91
- thiiranium intermediate 81
- thiirenium intermediate 104
- thioacetals 82
Sulfur shift, carbene 109
- carbocation 105
- sigmatropic [1, 5] 118
Sulfur ylides 4
- Sulfuranes 8
Superdienophiles 28
Superdipolarophiles 28
TTetrathiafulvalene 3
Thermolysis 135
Thia-Claisen 135
Thiadiazines 64
Thiamine (Vitamin B 1) 3
Thia-Payne rearrangement 99
Thiazetidines 133
Thiazines 133
Thiiranium 11, 77
- intermediates, addition of tethered nucleophiles 86
Thioacetals 82
- cyclic, ring expansion 110
- hydrolysis 12
Thioacetal S-oxide 7
Thioacetal S, S-dioxides 15
Thioacetal-supported domino process 14
Thioacylation 27
Thioamides 26
Thioanisole 10
Thiobutyrolactam 24
Thioketenes 26
Thione-enethiol tautomerism 27
Thionium ions 10
- , rearrangement 130
Thionocarbamates 26
Thionocarboxylic/thionocarbonic acid 26
Thiophene 3
Thiosulfonates 8
Thioureas 26
Tosylmethyl isocyanide 13
Total synthesis 35
Trithioorthocarboxylates 109
UUmpolung 14
VVinyl sulfone 21, 82
Vinyl sulfoxide 38
Vinyl thioethers 82
Vinyloxirane 5
YS-Ylides 4
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