DeutschesFachbuch.de : Organometallic and Coordination Chemistry of the Actinides

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Contents
Metallocene Organoactinide Complexes
M. Sharma • M. S. Eisen 1
Activation of Small Molecules by U(III) Cyclooctatetraene and Pentalene Complexes
O. T. Summerscales • F. G. N. Cloke 87
Highlights in Uranium Coordination Chemistry
S. C. Bart • K. Meyer 119
Author Index Volumes 101-130177
Subject Index 189
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Subject Index
AActinide, homoleptic 156
Actinide butadiene 69
Actinide carbonyl 99
Actinide complexes, synthesis/reactivity 4
- trivalent Cp 4
Actinide diene, ring inversion 70
Actinide dinitrogen 163
Activation 87
An(IV) tris cyclopentedienyl 53
Arene ligands 4
Azobenzene 12
BBis(cyclopentadienyl)actinides 71
Bis(cyclopentadienyl)thorium dialkyl 72
- 1, 2-Bis(dimethylphosphino)ethane 19
- 2, 6-Bis(imidazolylidene)pyridine 144
Bis(pentalene) U(IV) 90
Bis(pentamethylcyclopentadienyl) derivatives, thorium/uranium 53
Bis(pentamethylcyclopentadienyl) metallocene dithiolates 68
Bis(pentamethylcyclopentadienyl)thorium dialkyl 72
Bis(pentamethylcyclopentadienyl)uranium 32, 64
Bis(substituted cyclopentadinyl)actinide(IV) 56
Bis(trimethylsilyl)squarate 107
Bis-arylactinide 72
Bridging complexes 20
CCarbamoyl methyl sulfoxide ligands, bifunctional 135
Carbocycles, silylated eight-membered 91
Carbon dioxide 108, 167
Carbon monoxide 98, 166
Chalcogen bridged uranium(IV) complexes 23
Chalcogen-containing ligands 149
3-Chloropyridine 27
Coordination chemistry 119
Copper 159
Croconate 102
Cyanoimides 140
Cyclohexadienyl 4
Cyclooctatetraene (COT) 87
- U(III), mixed sandwich 89
Cyclooctatetraenyl 4
Cyclopentadienyl 4
- permethylated 8
Cyclopentadienyl thallium 36
Cyclopentadienyl U(III) isocyanide complexes 31
Cyclopentadienyl/dithiolene 33
DDeltate 103
- , formation 99- 5, 6-Dihydro-1, 4-dithiin-2, 3-dithiolate 33
- 1, 3-Dimesitylimidazole-2-ylidene 136
- 4-Dimethylaminopyridine 19- 3, 5-Dimethylpyrazine 27
Dinitrogen 96
Diorganophosphido actinide 68
Dithiolene 149
EElectronic spectroscopy 95
Ethyne diolate 104
FFischer-Tropsch 106
HHalide bridge U(III) complexes 21
Hexakisamido uranium 140
Hydrides ligands 4
Hydroamination/cyclization 122
Hydrocarbyls 4
IIndenyl 4
Isocyanate actinide 133
Isocyanates 112
Isocyanides adducts, uranium(III) metallocenes 31
KK/18-crown-6/benzene 14
LLanthanides 35
Lewis bases, affinity 25
Ligand cone angles 3
Ligands, multiply bonded 130
- 3, 5-Lutidine 27
MMacrocyclic ligands 122
Metal ligand back donation 28
Metallocene complexes 1
Molecular and electronic structure 119
Mono(cyclopentadienyl) uranium(III) 34
Multimetallic systems, uranium 158
NNitrogen donor ligands 140
OOrganoactinides 1
Organoimido ligands 65
Organouranium(III) amide 18
Oxocarbons, CO 102
- U(IV)-bound, functionalisation/extraction 106
PPentalene 87
Pentalene complexes 89
Phosphaalkyne 110
Phosphine imides 52
Phospholyl 4
Phosphorous species 110
- 3-Picoline 27
Plutonium 30
Poly(thioimidazolyl)borate 124
Pyrazine 27
Pyridazine 27
Pyrimidine 27
RReduction chemistry 87
Rhodizonate 102
SSalen ligands 138
Small molecules 87
- activation 96, 119
Squarate 103
- , formation 104
Steric coordination number 4
Sterically induced reduction (SIR) 1, 10
Sulfur ligands 135
TTetrahydrofuran (THF) adducts 5
Tetrahydrothiophene 19
Tetrakis(cyclopentadienyl) ligand 35
Tetrakis(dithiolene) 151
Tetramethylfulvene 9
Tetravalent chemistry 35
Thorium 2
Thorium butadiene 69
Thorium hydrocarbyls, CO insertion 48
Thorium(IV) tetraazamacrocycle 61
Transition metal-phosphine imine 52- 5-Triazine 27
Tri(cyclopentadienyl)AnX 38
Trimethylphosphine 19
Tris(N-tert-butylanilide) 145
Tris-Cp complexes 32
Tris(cyclopentadienyl)actinides 71
Tris(cyclopentadienyl)diethylaminouranium 41
Tris(cyclopentadienyl)thorium 8
Tris(1, 1'-ferrocenylene) 161
Tris(indenyl)thorium 37
Tris(indenyl)uranium 37
Tris(pyrazol-l-yl)hydroborate 124
Trithiacrown 130-1, 4, 7-Trithiacydononane 130
UU-CO-U 166
UI 3, solvent-free 121
UI 3 (bipy)2 (py) 122
U-Mo dinitrogen 163
Uranium 87, 119
- , multimetallic systems 158
Uranium azide, homoleptic 172
Uranium coordination chemistry 120
Uranium pentalene 165
Uranium pentamethylcyclopentadienyl 17
Uranium phosphorus complexes 49
Uranium precursors 122
Uranium silyl, non-metallocene 145
Uranium thiolate 152
Uranium-nitrogen multiple bond 51
Uranium-pyridyl 124
Uranium(III) 122
- halide bridge 21
Uranium(III) acetonitrile salt 122
Uranium(III) cyclooctatetraene, mixed sandwich 89
Uranium(III) nitrile 112
Uranium(III) pentamethylcyclopentadienyl 9
Uranium(III) thiolato complexes 25
Uranium(IV) 143 chalcogen bridged 23
Uranium(IV) bis(l, l'-diamidoferrocene)162
Uranium(IV) dithiolene 149
Uranium(IV) halide 122
Uranium(IV) organoimido 66
Uranium(IV) phosphoylide 50
Uranium(IV) triflate 122
Uranium(IV)-bound oxocarbons, functionalisation/extraction 106
Uranium(V) imido 142
Uranocene 124
Uranyl ion 130
ZZirconocene-dinitrogen 104
Zr/U 160
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